Another thing that's very noticeable while exploring the
Posterousphere (sorry) is that the site's developers are listening to
the users. I emailed them a question and they responded very quickly.
They also post comments on user sites where appropriate.
A short amount of searching showed me that they plan to add per-site
Autopost settings soon (so you can have more than one Posterous, each
with different Autopost options), as well as support for Markdown
(which would be a huge improvement, in my opinion).
Edd said that "Posterous gives me warm feelings":
http://bitten.twiceshy.org/posterous-gives-me-warm-feelings
and I see exactly what he means. It feels natural, useful, and easy.
(That paragraph there is why Markdown would be good.)
Another unexpected thing: the total lack of template customisation
feels like a good thing! Less for me to fiddle with. What's there is
simple and works.